Science & Technology Agricultural Science

Soil Fertility, Fertilisers and Manures

Essential plant nutrients, NPK and deficiency symptoms, soil pH, urea, DAP and nano urea, manures and biofertilisers, and balanced fertilisation for CGPSC Mains GS-II.

16 min read Updated Oct 2026 #soil fertility#npk#fertilisers

Prerequisites

The Hook: Khaira in the Paddy Nursery

Connect

A farmer in Bemetara notices that, a few weeks after transplanting, patches of his paddy have turned rusty brown and stunted. His neighbour says: “Add more urea.” He does, and nothing improves. The agricultural extension officer looks once and says khaira (खैरा). The crop is short of zinc, not nitrogen. A small dose of zinc sulphate fixes it.

The lesson is older than the Green Revolution: a plant is held back by whichever nutrient is most lacking, and adding more of another does nothing. How many nutrients does a crop need? Why does India use so much urea? Can cow dung and bacteria replace chemical fertilisers? This page answers those questions.

Why it matters: Mains GS-II asks about soil health, NPK imbalance, nano fertilisers, biofertilisers and integrated nutrient management. GS-III (economy) asks about fertiliser subsidy; that policy side is in Agriculture and the Economy. Here the focus is the science.


Soil Fertility: the Basics

Soil fertility (मृदा उर्वरता) is the soil’s ability to supply nutrients in adequate amounts and balance. Soil productivity is its ability to produce crops, which also depends on water, climate and management. A soil can be fertile but unproductive (for example, fertile but waterlogged).

The 17 essential elements

A nutrient is essential if the plant cannot complete its life cycle without it, it cannot be replaced by another element, and it is directly involved in the plant’s metabolism. Seventeen elements meet these criteria:

GroupElementsSource
Non-mineralCarbon (C), hydrogen (H), oxygen (O)Air and water
Primary macronutrientsNitrogen (N), phosphorus (P), potassium (K)Soil and fertilisers; needed in the largest amounts
Secondary macronutrientsCalcium (Ca), magnesium (Mg), sulphur (S)Soil, lime, gypsum
MicronutrientsIron (Fe), manganese (Mn), zinc (Zn), copper (Cu), boron (B), molybdenum (Mo), chlorine (Cl), nickel (Ni)Needed in tiny amounts, but just as essential
Liebig's Law of the Minimum
Justus von Liebig (19th century) stated that growth is controlled not by the total nutrients available but by the scarcest one. It is often pictured as a barrel with staves of unequal length: water spills over the shortest stave. In the hook, zinc was the shortest stave, so more nitrogen could not help.

What each major nutrient does

NutrientMain role in the plantDeficiency symptomMobility
Nitrogen (N)Part of proteins, nucleic acids and chlorophyll; drives leafy growthYellowing (chlorosis) of older leaves first; stunted growthMobile in plant, so old leaves show it first
Phosphorus (P)Energy transfer (ATP), nucleic acids, root growth, flowering, seed formationPurple or dark green leaves; poor roots; delayed maturityMobile
Potassium (K)Opens and closes stomata; enzyme activation; water regulation; disease and lodging resistance; grain qualityScorching of leaf margins in older leaves; weak stemsMobile
Sulphur (S)Part of some amino acids; oil content in oilseedsYellowing of young leavesLess mobile
Zinc (Zn)Enzyme activation; growth hormonesKhaira disease of rice (rusty brown patches); “little leaf”Immobile
Iron (Fe)Chlorophyll formationChlorosis of young leaves with green veins (interveinal)Immobile
Boron (B)Cell wall formation; pollen and seed setHollow stem, poor seed set; “brown heart” in some root cropsImmobile
Molybdenum (Mo)Part of nitrogenase; nitrogen metabolismWhiptail of cauliflowerModerately mobile

Rule of thumb: deficiency of a mobile nutrient shows first on older (lower) leaves, because the plant moves it to new growth. Deficiency of an immobile nutrient shows on younger (upper) leaves.

Soil reaction (pH) and how to correct it

Problem soilCauseCorrection
Acidic soil (pH below about 6)High rainfall leaches bases; laterite and red soilsLiming (चूना) with calcium carbonate raises pH; makes P and Mo more available
Saline soilExcess soluble saltsLeaching with good-quality water; drainage
Alkaline or sodic soil (high pH, excess sodium)Poor drainage, canal over-irrigation in dry areasGypsum (calcium sulphate) replaces sodium; then leaching. Pyrite can also be used

Chhattisgarh angle: Much of the state has red and yellow soils and lateritic Bhata soils, many of them acidic, especially in the Bastar plateau and the northern hills. These soils are also often low in phosphorus, and zinc deficiency is common in intensively cropped paddy. Liming, phosphorus and zinc management are therefore core advice from IGKV, Raipur.


Chemical Fertilisers

Common fertilisers and nutrient content

FertiliserNutrient contentTypeNotes
Urea46% NStraight (nitrogen)Most-used fertiliser in India; amide form, converted to ammonium and then nitrate in soil
Ammonium sulphateAbout 20–21% N + about 24% SStraight (N)Also supplies sulphur; acidifies soil
DAP (diammonium phosphate)18% N, 46% P₂O₅ComplexMain phosphatic fertiliser; largely imported or made from imported raw material
SSP (single super phosphate)16% P₂O₅ (plus sulphur and calcium)Straight (P)Made in India from rock phosphate; useful for oilseeds and pulses because of its sulphur
MOP (muriate of potash, potassium chloride)60% K₂OStraight (K)India has no commercial potash reserves, so it is wholly imported
NPK complexese.g. 10:26:26, 12:32:16ComplexSupply all three primary nutrients
Zinc sulphateZinc (and sulphur)MicronutrientCorrects khaira in rice

Straight fertilisers supply one primary nutrient. Complex fertilisers supply two or more through a chemical reaction. Mixed fertilisers are physical blends.

The nitrogen problem: why urea is overused and wasted

India’s crops recover only a modest share of the nitrogen applied; nitrogen-use efficiency in Indian field conditions is commonly estimated at about 30–50%. The rest is lost by:

Loss pathwayWhat happensEnvironmental cost
VolatilisationUrea turns into ammonia gas, which escapes, especially from wet surface-applied urea in heatAir pollution
LeachingNitrate (NO₃⁻), which is negatively charged and not held by soil, washes below the root zoneGroundwater nitrate pollution; “blue baby syndrome” (methaemoglobinaemia) in infants
DenitrificationIn waterlogged soil, bacteria turn nitrate into nitrogen gases, including nitrous oxide (N₂O)N₂O is a powerful greenhouse gas
RunoffFertiliser washes into water bodiesEutrophication (algal blooms)

Why urea is overused: urea is priced far below cost under the fertiliser subsidy, while phosphatic and potassic fertilisers moved to Nutrient Based Subsidy (NBS) in 2010 and became costlier. Farmers respond by using more nitrogen and less P and K. The result is a skewed NPK ratio.

The 4:2:1 benchmark
The generally recommended N:P:K ratio of 4:2:1 is a broad national benchmark (the right ratio varies by crop and soil). India’s actual use has stayed far more nitrogen-heavy: seasonal ratios of roughly 10:4:1 were reported for kharif 2023 and 2024. Excess N with too little P, K and micronutrients lowers response to fertiliser, degrades soil and wastes subsidy.

Making fertiliser smarter

InnovationWhat it isScience
Neem-coated urea (नीम लेपित यूरिया)Mandatory for all domestically produced and imported urea since 2015Neem oil compounds slow nitrification, so nitrogen stays in the ammonium form longer and is lost less. Also stopped diversion of subsidised urea to industry
Nano urea (liquid)Launched by IFFCO in June 2021; nano DAP followed in 2023; both notified under the Fertiliser Control Order, 1985Nanoscale nitrogen particles sprayed on leaves are claimed to be absorbed more efficiently. A 500 ml bottle is marketed as replacing one bag of urea. Independent field trials have questioned the yield claims, so present it as promising but still debated
Slow- and controlled-release fertilisersCoated urea (e.g. sulphur- or polymer-coated)Release nutrients over weeks to match crop demand
Customised and fortified fertilisersBlends with micronutrients, zinc-coated ureaMatch the soil’s actual deficiencies
FertigationFertiliser dissolved in drip irrigation waterPlaces nutrients at the roots in small doses

Policy tools linked to soil science

MeasureYearScientific purpose
Nutrient Based Subsidy (NBS)2010Subsidy fixed per kg of N, P, K and S in P and K fertilisers. Urea is outside NBS
Soil Health Card Scheme (मृदा स्वास्थ्य कार्ड)Launched 19 February 2015 at Suratgarh, RajasthanSoil tested for 12 parameters (N, P, K, S, Zn, Fe, Cu, Mn, B, pH, EC, organic carbon); crop-wise fertiliser advice
Neem-coated urea2015Slower nitrification, less diversion
One Nation One Fertiliser ("Bharat" brand)2022Single brand for subsidised fertilisers
PM-PRANAMApproved 2023Rewards states that reduce chemical fertiliser use compared with their past average, with part of the subsidy saved
World Soil Day5 December (UN)Awareness of soil health

Manures: Organic Sources of Nutrients

Manures (खाद) are organic materials of plant or animal origin. They supply nutrients in small amounts but greatly improve soil structure, water-holding capacity, cation exchange capacity and soil biological activity.

TypeExamplesTypical nutrient contentNotes
Bulky organic manuresFarmyard manure (FYM) (गोबर खाद), compostFYM roughly 0.5% N, 0.2% P₂O₅, 0.5% K₂OLarge quantities needed; main value is organic matter
Vermicompost (केंचुआ खाद)Organic waste digested by earthworms, mainly Eisenia fetida (red wiggler)Richer than FYM; contains growth-promoting substancesFaster than ordinary composting
Green manure (हरी खाद)Fast-growing legumes ploughed into the soil while green: sunhemp (सनई), dhaincha (ढैंचा, Sesbania)Adds N and organic matterSesbania rostrata forms stem nodules and suits waterlogged paddy fields
Green leaf manureLeaves of Glyricidia, karanj, neem collected and incorporatedAdds N and organic matterUseful where land cannot be spared for a green manure crop
Concentrated organic manuresOilcakes (neem, castor, groundnut cake), bone meal, fish mealHigher nutrient contentNeem cake also has pest-repellent and nitrification-inhibiting effects
Chhattisgarh: gauthans and vermicompost
Under the Godhan Nyay Yojana (गोधन न्याय योजना), launched on Hareli, 20 July 2020, the state government bought cow dung at ₹2 per kg, and women’s self-help groups turned it into vermicompost at village gauthans under the Suraji Gaon Yojana (Narwa–Garwa–Ghurwa–Bari). Scientifically it linked livestock, organic manure and soil carbon; in practice, questions were raised about compost quality and costs. See Agricultural Schemes in Chhattisgarh.

Biofertilisers

Biofertilisers (जैव उर्वरक) are preparations of living microorganisms that increase the availability of nutrients to plants, by fixing nitrogen, dissolving phosphorus or helping roots absorb nutrients. They are regulated as fertilisers under the Fertiliser Control Order, 1985.

BiofertiliserOrganism typeHow it helpsCrops
RhizobiumSymbiotic bacterium in root nodulesFixes nitrogenLegumes only (gram, soybean, arhar, groundnut); crop-specific strains
AzotobacterFree-living, aerobic bacteriumFixes nitrogen; produces growth hormonesCereals, vegetables, cotton
AzospirillumAssociative bacterium living around and in rootsFixes nitrogenCereals and millets: maize, sorghum, ragi, rice
Acetobacter (Gluconacetobacter diazotrophicus)Endophyte inside the plantFixes nitrogenSugarcane
Blue-green algae (cyanobacteria)Free-living: Anabaena, Nostoc, TolypothrixFix nitrogen in standing waterPaddy
AzollaWater fern with the cyanobacterium Anabaena azollae living in its leavesFixes nitrogen; also used as cattle feedPaddy
Phosphate-solubilising bacteria (PSB)Bacillus, PseudomonasDissolve fixed (insoluble) phosphateAll crops
Mycorrhiza (VAM/AM fungi)Fungus forming a symbiosis with rootsFungal threads extend the root system; improve phosphorus and water uptakeMost crops and tree nurseries
Potash- and zinc-solubilising bacteriaVarious bacteriaMake K and Zn availableAll crops

Limitations: they are living products, so they have a short shelf life, are sensitive to heat and storage, are crop- or strain-specific (Rhizobium especially), and their effect depends on soil conditions. They supplement chemical fertilisers; they rarely replace them fully.


Integrated Nutrient Management (INM)

INM (एकीकृत पोषक तत्व प्रबंधन) combines chemical fertilisers + organic manures + biofertilisers + crop residues + legumes in rotation, based on soil testing, to supply nutrients in balance while keeping soil healthy.

graph LR
    A["Soil test
(Soil Health Card)"] --> B["Balanced chemical
fertilisers (NPK + Zn, S)"] A --> C["Organic manures
(FYM, vermicompost, green manure)"] A --> D["Biofertilisers
(Rhizobium, PSB, BGA, Azolla)"] A --> E["Legumes in rotation
and residue recycling"] B --> F["INM: higher yield,
healthier soil, less waste"] C --> F D --> F E --> F
Mains analysis: why soil health is declining
  • Imbalanced fertilisation: urea-heavy, P and K short, micronutrients ignored
  • Falling soil organic carbon: residue burning, little manure, intensive tillage
  • Multi-nutrient deficiencies: zinc, sulphur and boron deficiencies widespread
  • Acidification and salinisation: acid soils in high-rainfall regions (including parts of Chhattisgarh), salinity in canal-irrigated dry areas
  • Policy bias: cheap urea, weak extension, soil tests not followed by action
  • Way forward: INM, soil-test-based dosing, neem-coated and slow-release products, biofertilisers, green manuring, rational pricing of nutrients

Memory Tricks

The 17 elements: 'C HOPKiNS CaFe Mg' plus micronutrients
The classic line “C. HOPKiNS CaFe, Mighty good” gives C, H, O, P, K, N, S, Ca, Fe, Mg. Add the remaining micronutrients with “Zinc and Copper Bring Many Molybdenum Chlorine Nickel”: Zn, Cu, B, Mn, Mo, Cl, Ni. Total: 17.
NPK jobs: 'Up, Down and All-Around'
N = Up (leaves and shoots) · P = Down (roots, plus flowers and seeds) · K = All-around (stomata, water balance, disease resistance, grain quality).
Fertiliser numbers: '46, 18-46, 16, 60'
Urea 46 (N) · DAP 18-46 (N-P₂O₅) · SSP 16 (P₂O₅) · MOP 60 (K₂O).

Don’t Confuse

ThisvsThat
Soil fertility: nutrient supplyvsSoil productivity: actual crop output
N deficiency: chlorosis of older leavesvsFe deficiency: chlorosis of younger leaves
Liming: for acidic soilsvsGypsum: for alkaline/sodic soils
Rhizobium: symbiotic, legumes, root nodulesvsAzotobacter: free-living; Azospirillum: associative, cereals
Azolla: a water fernvsAnabaena: the cyanobacterium inside it that fixes N
Manure: organic, bulky, improves soil structurevsFertiliser: concentrated nutrient source, usually chemical
NBS (2010): covers P and K fertilisersvsUrea: outside NBS, fixed low price

Common Mistakes

MCQ and Mains traps
  • “Azolla fixes nitrogen by itself.” Imprecise. The cyanobacterium Anabaena azollae in its leaves fixes nitrogen.
  • “Rhizobium can be used for any crop.” False. It is specific to legumes, and to particular legume groups.
  • “India mines its own potash.” False. MOP is wholly imported.
  • “Khaira disease of rice is caused by a fungus.” False. It is a zinc deficiency disorder.
  • “Neem coating adds nitrogen.” False. Neem coating slows nitrification and so reduces losses; it adds no nutrient worth counting.
  • “Nano urea’s yield benefit is settled science.” Avoid this. Its yield claims have been questioned by independent trials; write “debated”.

Practice

All questions below are original practice questions written in CGPSC style. They are not previous-year questions.

Level 1: Foundation

  1. The nitrogen content of urea is ______ per cent.
  2. Khaira disease of rice is caused by deficiency of ______.
  3. Acidic soils are corrected by applying ______, and sodic soils by applying ______.
Answers
  1. 46 per cent.
  2. Zinc.
  3. Lime; gypsum.

Level 2: Prelims-style MCQs

Q1. Consider the following statements about biofertilisers:

  1. Azotobacter is a free-living nitrogen-fixing bacterium.
  2. Azolla is a cyanobacterium widely used in paddy fields.
  3. Mycorrhizal fungi mainly improve the uptake of phosphorus.

Which of the statements given above is/are correct?

  • (a) 1 only
  • (b) 1 and 3 only
  • (c) 2 and 3 only
  • (d) 1, 2 and 3
Answer and explanation
(b) 1 and 3 only. Azotobacter is free-living and aerobic. Azolla is a water fern, not a cyanobacterium; the cyanobacterium Anabaena azollae lives inside its leaves and fixes the nitrogen. Mycorrhizal fungi extend the root system and are best known for improving phosphorus uptake.

Q2. Match List I (Deficiency) with List II (Symptom or disorder):

List IList II
A. Nitrogen1. Whiptail of cauliflower
B. Zinc2. Yellowing of older leaves first
C. Molybdenum3. Scorching of leaf margins
D. Potassium4. Khaira disease of rice
  • (a) A-2, B-4, C-1, D-3
  • (b) A-3, B-4, C-1, D-2
  • (c) A-2, B-1, C-4, D-3
  • (d) A-2, B-4, C-3, D-1
Answer and explanation
(a) A-2, B-4, C-1, D-3. Nitrogen is mobile, so older leaves yellow first. Zinc deficiency causes khaira in rice. Molybdenum deficiency causes whiptail in cauliflower. Potassium deficiency scorches leaf margins.

Q3. Neem coating of urea improves nitrogen-use efficiency mainly by:

  • (a) Adding extra nitrogen from neem oil
  • (b) Slowing the conversion of ammonium to nitrate in the soil
  • (c) Increasing the solubility of urea
  • (d) Killing nitrogen-fixing bacteria
Answer and explanation
(b). Neem compounds act as nitrification inhibitors. Nitrogen stays longer as ammonium, which soil particles hold, so less is lost as leached nitrate or as nitrous oxide. Neem oil adds negligible nitrogen.

Q4. Which of the following fertilisers is entirely imported into India because the country has no commercially viable reserves of its raw material?

  • (a) Urea
  • (b) Single super phosphate
  • (c) Muriate of potash
  • (d) Ammonium sulphate
Answer and explanation
(c) Muriate of potash. India has no commercially exploited potash reserves, so MOP is wholly imported. Urea is mostly made in India (from natural gas, partly imported). SSP is made in India from rock phosphate.

Q5. Under the Soil Health Card Scheme, which of the following is not among the parameters tested?

  • (a) Organic carbon
  • (b) Electrical conductivity
  • (c) Zinc
  • (d) Soil microbial DNA
Answer and explanation
(d). The card reports 12 parameters: N, P, K, S, Zn, Fe, Cu, Mn, B, pH, electrical conductivity and organic carbon. Microbial DNA is not tested.

Level 3: Mains Answer Writing

Q1. (60 words) What are biofertilisers? Name two and state their limitations.

Model answer outline
  • Living microorganisms that make nutrients available by fixing nitrogen, solubilising phosphate or extending root uptake.
  • Examples: Rhizobium (legume nodules), Azolla–Anabaena (paddy), PSB, mycorrhiza.
  • Limitations: short shelf life, heat-sensitive, crop/strain-specific, variable field results; they supplement, not replace, fertilisers.

Q2. (150–200 words) “India’s soils are hungry for balance, not for more fertiliser.” Discuss with reference to the NPK imbalance and integrated nutrient management.

Model answer outline
  • Intro: Fertiliser use rose with the Green Revolution, but the response per kg has fallen; the use pattern is skewed towards nitrogen.
  • The imbalance: benchmark N:P:K of 4:2:1 versus seasonal ratios of roughly 10:4:1 in 2023–24; cheap urea outside NBS (2010) versus costlier P and K.
  • Scientific costs: Liebig’s law, so excess N cannot offset P, K, S or Zn deficits; N losses through volatilisation, leaching (groundwater nitrate) and denitrification (N₂O); falling soil organic carbon; widespread zinc and sulphur deficiencies.
  • INM as the answer: soil-test-based doses (Soil Health Card, 2015); neem-coated and slow-release urea; FYM, vermicompost and green manure; biofertilisers; legumes in rotation; micronutrient correction.
  • Chhattisgarh angle: acidic red-yellow and Bhata soils need liming and phosphorus; zinc deficiency (khaira) in intensive paddy; gauthan vermicompost under Godhan Nyay (2020) as an organic input experiment.
  • Conclusion: Balance and soil biology, supported by rational nutrient pricing (PM-PRANAM incentives), not more urea, will raise productivity.

Quick Revision Table

FactDetail
Essential elements17: C, H, O + N, P, K + Ca, Mg, S + Fe, Mn, Zn, Cu, B, Mo, Cl, Ni
Law of the MinimumLiebig: the scarcest nutrient limits growth
Mobile-nutrient deficiencyOlder leaves first (N, P, K)
Urea / DAP / SSP / MOP46% N / 18-46 / 16% P₂O₅ / 60% K₂O
MOPWholly imported
N lossesVolatilisation, leaching, denitrification (N₂O), runoff
Benchmark NPK4:2:1
NBS2010; urea excluded
Neem-coated ureaMandatory 2015; nitrification inhibitor
Nano ureaIFFCO, June 2021; nano DAP 2023; yield claims debated
Soil Health Card19 Feb 2015, Suratgarh (Rajasthan); 12 parameters
PM-PRANAM2023; incentive to states to cut chemical fertiliser
Acid / sodic soilLime / gypsum
Khaira (rice)Zinc deficiency
Vermicompost wormEisenia fetida
Green manuresSunhemp, dhaincha; Sesbania rostrata stem nodules
Paddy biofertilisersBGA (Anabaena, Nostoc), Azolla–Anabaena azollae
Sugarcane biofertiliserAcetobacter (Gluconacetobacter)

Key Takeaways

Key Takeaways
  1. Seventeen elements are essential; the scarcest one limits yield (Liebig).
  2. Nitrogen is cheap and overused; much of it is lost to air and water, causing pollution and greenhouse gases.
  3. Neem coating, slow-release forms, soil testing and balanced NPK raise efficiency; nano urea is promising but debated.
  4. Manures build soil structure and carbon; biofertilisers add nitrogen and phosphorus biologically but are living, specific and short-lived.
  5. Integrated Nutrient Management is the scientific synthesis Mains answers should end on.

What’s Next

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